The crystal structure of perdeuterated methanol hemiammoniate (CD3OD center dot 0.5ND(3)) determined from neutron powder diffraction data at 4.2 and 180 K

The crystal structure of perdeuterated methanol hemiammoniate, CD3OD center dot 0.5ND(3), has been solved from neutron powder diffraction data collected at 4.2 and 180 K. The structure is orthorhombic, space group Pn2(1)a (Z = 4), with unit-cell dimensions a = 12.70615 (16), b = 8.84589 (9), c = 4.73876 (4) angstrom, V = 532.623 (8) angstrom(3) [rho(calc) = 1149.57 (2) kg m(-3)] at 4.2 K, and a = 12.90413 (16), b = 8.96975 (8), c = 4.79198 (4) angstrom, V = 554.656 (7) angstrom(3) [rho(calc) = 1103.90 (1) kg m(-3)] at 180 K. The crystal structure was determined by ab initio methods from the powder data; atomic coordinates and isotropic displacement parameters were subsequently refined by the Rietveld method to R-p similar or equal to 2% at both temperatures. The crystal structure comprises a three-dimensionally hydrogen-bonded network in which the ND3 molecules are tetrahedrally coordinated by the hydroxy moieties of the methanol molecule. This connectivity leads to the formation of zigzag chains of ammonia-hydroxy groups extending along the c axis, formed via N-D center dot center dot center dot O hydrogen bonds; these chains are cross-linked along the a axis through the hydroxy moiety of the second methanol molecule via N-D center dot center dot center dot O and O-D center dot center dot center dot O hydrogen bonds. This 'bridging' hydroxy group in turn donates an O-D center dot center dot center dot N hydrogen bond to ammonia in adjacent chains stacked along the b axis. The methyl deuterons in methanol hemiammoniate, unlike those in methanol monoammoniate, do not participate in hydrogen bonding and reveal evidence of orientational disorder at 180 K. The relative volume change on warming from 4.2 to 180 K, Delta V/V, is + 4.14%, which is comparable to, but more nearly isotropic (as determined from the relative change in axial lengths, e. g. Delta a/a) than, that observed in deuterated methanol monohydrate, and very similar to what is observed in methanol monoammoniate

Crystal structures and thermal expansion of alpha-MgSO4 and beta-MgSO4 from 4.2 to 300 K by neutron powder diffraction

Detailed neutron powder diffraction measurements have been carried out on two polymorphs of anhydrous magnesium sulfate, alpha-MgSO4 and beta-MgSO4. alpha-MgSO4 is orthorhombic, space group Cmcm (Z = 4); at 4.2 K the unit-cell dimensions are a = 5.16863 (3), b = 7.86781 (5), c = 6.46674 (5) angstrom, V = 262.975 (2) angstrom(3) [rho(calc) = 3040.16 (2) kg m(-3)], and at 300 K, a = 5.17471 (3), b = 7.87563 (5), c = 6.49517 (5) angstrom, V = 264.705 (2) angstrom(3) [rho(calc) = 3020.29 (2) kg m(-3)]. The axial and volumetric thermal expansion coefficients are positive at all temperatures and exhibit no unusual behaviour. Structures were refined at 4.2 and 300 K to R-P < 3%; less precise structural parameters were determined during warming from 4.2 to 300 K. beta-MgSO4 has a more complex structure, crystallizing in space group Pbnm (Z = 4); the unit-cell dimensions at 4.2 K are a = 4.73431 (8), b = 8.58170 (12), c = 6.67266 (11) angstrom, V = 271.100 (5) angstrom(3) [rho(calc) = 2949.04 (5) kg m(-3)], and at 300 K, a = 4.74598 (7), b = 8.58310 (10), c = 6.70933 (10) angstrom, V = 273.306 (4) angstrom(3) [rho(calc) = 2925.42 (4) kg m(-3)]. The thermal expansivities of the a and c axes, and the volumetric thermal expansion coefficient, are positive at all temperatures and normally behaved. However, the thermal expansion of the b axis is both very small and negative below similar to 125 K. Structural and thermal motion parameters for beta-MgSO4 as a function of temperature are also reported