Anionic and cationic redox and interfaces in batteries: Advances from soft X-ray absorption spectroscopy to resonant inelastic scattering

Recent advances in battery science and technology have triggered both the challenges and opportunities on studying the materials and interfaces in batteries. Here, we review the recent demonstrations of soft X-ray spectroscopy for studying the interfaces and electrode materials. The focus of this review is on the recently developed mapping of resonant inelastic X-ray scattering (mRIXS) as a powerful probe of battery chemistry with superior sensitivity. Six different channels of soft X-ray absorption spectroscopy (sXAS) are introduced for different experimental purposes. Although conventional sXAS channels remain effective tools for quantitative analysis of the transition-metal states and surface chemistry, we elaborate the limitations of sXAS in both cationic and anionic redox studies. Particularly, based on experimental findings in various electrodes, we show that sXAS is unreliable for studying oxygen redox. We then demonstrate the mRIXS as a reliable technique for fingerprinting oxygen redox and summarize several crucial observations. We conclude that mRIXS is the tool-of-choice to study both the practical issue on reversibility of oxygen redox and the fundamental nature of bulk oxygen states. We hope this review clarifies the popular misunderstanding on oxygen sXAS results of oxide electrodes, and establishes a reliable technique for detecting oxygen redox through mRIXS

Modular transformation and twist between trigonometric limits of sl(n)sl(n) elliptic R-matrix

We study the modular transformation of ${\bf Z}_n$-symmetric elliptic R-matrix and construct the twist between the trigonometric degeneracy of the elliptic R-matrix.Comment: 8 pages, latex, reference revise

Electron yields from spacecraft materials

Photoyields and secondary electron emission (SEE) characteristics were determined under UHV conditions for a group of insulating materials used in spacecraft applications. The SEE studies were carried out with a pulsed primary beam while photoyields were obtained with a chopped photon beam from a Kr resonance source with major emission at 123.6 nm. This provides a photon flux close to that of the Lyman alpha in the space environment. Yields per incident photon are obtained relative to those from a freshly evaporated and air oxidized Al surface. Results are presented for Kapton, FEP Teflon, the borosilicate glass covering of a shuttle tile, and spacesuit outer fabric

Determinant representations of scalar products for the open XXZ chain with non-diagonal boundary terms

With the help of the F-basis provided by the Drinfeld twist or factorizing F-matrix for the open XXZ spin chain with non-diagonal boundary terms, we obtain the determinant representations of the scalar products of Bethe states of the model.Comment: Latex file, 28 pages, based on the talk given by W. -L. Yang at Statphys 24, Cairns, Australia, 19-23 July, 201

AC Oscillation of a Spin Soliton Driven by a Constant Force

The phenomena of AC oscillation generated by a DC drive, such as the famous Josephson AC effect in superconductors and Bloch oscillation in solid physics, are of great interest in physics. Here we report another example of such counter-intuitive phenomenon that a spin soliton in a two-component Bose-Einstein condensate is driven by a constant force: The initially static spin soliton first moves in a direction opposite to the force and then changes direction, showing an extraordinary AC oscillation in a long term. In sharp contrast to the Josephson AC effect and Bloch oscillation, we find that the nonlinear interactions play important roles and the spin soliton can exhibit a periodic transition between negative and positive inertial mass even in the absence of periodic potentials. We then develop an explicit quasiparticle model that can account for this extraordinary oscillation satisfactorily. Important implications and possible applications of our finding are discussed.Comment: 9 pages, 6 figure