Nonlinear electrokinetics at large voltages

The classical theory of electrokinetic phenomena assumes a dilute solution of point-like ions in chemical equilibrium with a surface whose double-layer voltage is of order the thermal voltage, kBT/e=25 mV. In nonlinear 'induced-charge' electrokinetic phenomena, such as ac electro-osmosis, several volts ≈100kBT/e are applied to the double layer, and the theory breaks down and cannot explain many observed features. We argue that, under such a large voltage, counterions 'condense' near the surface, even for dilute bulk solutions. Based on simple models, we predict that the double-layer capacitance decreases and the electro-osmotic mobility saturates at large voltages, due to steric repulsion and increased viscosity of the condensed layer, respectively. The former suffices to explain observed high-frequency flow reversal in ac electro-osmosis; the latter leads to a salt concentration dependence of induced-charge flows comparable to experiments, although a complete theory is still lacking.National Science Foundation (U.S.) (Grant No. DMS-0707641)United States. Army Research Office. Institute for Soldier Nanotechnologies (Contract No. DAAD- 19-02-0002

The young massive stellar cluster associated to RCW121

We report NIR broad and narrow band photometric observations in the direction of the IRAS17149-3916 source that reveal the presence of a young cluster of massive stars embedded in an HII region coincident with RCW121. These observations, together with published radio data, MSX and Spitzer images were used to determine some of the physical parameters of the region. We found 96 cluster member candidates in an area of about 1.5 x 2.0 square arcmin, 30% of them showing excess emission in the NIR. IRS 1, the strongest source in the cluster with an estimated spectral type of O5V-O6V ZAMS based on the color-magnitude diagram, is probably the main ionizing source of the HII region detected at radio wavelengths. Using the integrated Brgamma and the 5 GHz flux densities, we derived a mean visual extinction AV=5.49 magnitudes. From the observed size of the Brgamma extended emission, we calculated the emission measure E and the electron density ne, characteristic of compact HII regions.Comment: 18 pages, 8 figures, accepted for publication on AJ (February/2006

Structure of short-range ordered aluminosilicates in andic horizons of volcanic soils

Very high levels of C content characterize Andic horizons of volcanic soils. Stabilization of organic matter is due to the presence of short-range ordered aluminosilicates (imogolites, allophanes or proto-imogolites). These phases are often characterized through selective chemical extractions from which the "allophane" content is calculated. However, chemical dissolutions preclude the characterization of the structure of the short-range ordered aluminosilicates. Imogolite is easily distinguishable because of its tubular structure, whereas allophane compounds-usually described as spheres-are harder to identify, especially because of their variable structure and occurrence patterns. In addition, the local structure of allophanes can be very similar to that of proto-imogolite (imogolite precursor). Strangely, this similarity is seldom considered in most characterization studies. In this context, our study focuses on the structure of two short range-ordered aluminosilicates of two different origins, from: (i) an Andosol B horizon (Andosol sample); and (ii) a weathered pumice grain (pumice sample). These natural samples were compared to a synthetic proto-imogolite. The three samples were analyzed using experimental tools that are commonly used for the identification of these nanophases (chemical composition, X-ray diffraction, nuclear magnetic resonance, Fourier transform infrared spectroscopy and transmission electron microscopy). The three samples exhibited the same local structure, but significant differences were observed at a larger scale. The pumice sample clearly showed ring-shaped particles, while the Andosol sample and the synthetic proto-imogolite were amorphous. Our results suggest that poorly ordered proto-imogolite, rather than allophanes, is present in Andosol horizons. (Résumé d'auteur

Classification of Reductive Monoid Spaces Over an Arbitrary Field

In this semi-expository paper we review the notion of a spherical space. In particular we present some recent results of Wedhorn on the classification of spherical spaces over arbitrary fields. As an application, we introduce and classify reductive monoid spaces over an arbitrary field.Comment: This is the final versio