Alaska mining and water quality

The Institute of Water Resources has sought financial assistance for some time in an attempt to initiate research relative to the impact of mining on water quality. Attempts were made as early as 1971 by Dr. Timothy Tilsworth and later by Dr. Donald Cook and Dr. Sage Murphy. These investigators anticipated growth in placer gold mining and the development of natural resources in Alaska during a period of national and environmental concern. The subsequent energy "crisis," the major increase in the price of gold on the world market, and dwindling nonrenewable resource supplies have resulted in large-scale mineral exploration in Alaska. This exploration, coupled with development of the trans-Alaska oil pipeline, has attracted considerable capital for potential investment and development in Alaska. Expected industrial growth has already started and major new projects are "just around the corner." Yet, as of 1976, no major research effort has occurred to determine the extent of or potential for water quality impacts from mining operations in Alaska. Recently a series of interdisciplinary research projects have been completed in Canada; however, the application of Canadian data to Alaskan problems is uncertain. Although, state and federal government agencies have been advised and are aware of this potential problem and lack of baseline data they have not sought out new information or rational solutions. Even now, with deadlines of Public Law 92-500 at hand, some regulatory agencies give the impression of attempting to ignore the situation. Interim limitations are proposed and permits are issued with no discernible rationale or basis. Data have not been obtained relative to the Alaskan mining operations and thus are not available for use in seeking solutions compatible with mining and environmental protection. Numbers appear to have been arbitrarily assigned to permits and water quality standards. When permits are issued, self-monitoring requirements are negligible or nonexistent. Nor have regulatory agencies demonstrated the ability or inclination to monitor mining operations or enforce permits and water quality standards. It was hoped that the project would bring together miners, environmentalists, and regulators in a cooperative effort to identify the problems and seek solutions. The investigators recognized the political sensitivity of the subject matter but proceeded optimistically. Relatively good cooperation, though not total, occurred early in the project. In April 1976, a symposium was held to exchange ideas and determine the state-of-the-art. Although the symposium had good attendance and an exchange of information occurred, the symposium itself was somewhat of a disappointment. With few exceptions, the participants aligned on one side or the other in preconceived fixed positions. Some even chose not to attend and were therefore able to avoid the issues. Little hard data was presented. Optimistically, some of the miners, environmentalists, and regulators are prepared to resolve their differences. This report, hopefully, will be of benefit to them. It is our experience that miners and environmentalists share a love of the land that is uniquely Alaska. We feel that technology is available for application to this problem for those who care about doing the job right in the "last frontier." Whether or not it will be effectively applied to protect Alaska's water resources is a question which remains unanswered.The work upon which this report is based was supported in part by funds provided by the United States Department of the Interior, Office of Water Resources Research Act of 1964, Public Law 88-379, as amended (Project A-055-ALAS)

Cold climate water/wastewater transportation and treatment - a bibliography: completion report

This bibliography contains 1,400 citations, including published and unpublished papers, on cold-climate water and wastewater transportation and treatment systems. Sources listed include state and federal agency files which contain information on systems in Alaskan communities and the Alyeska Pipeline Service Company camps. References to systems in other northern countries are also included. The objectives of this study were to identify causes of the failure of Alaskan water and wastewater treatment and transportation facilities and to seek methods for design improvements. Originally, the investigators contemplated an evaluation of systems performance in remote areas in relation to the original conception, planning, design, and construction. Because of the tremendous amount of literature examined, the evaluation was undertaken in a subsequent study, "Alaska Wastewater Treatment Technology" (A-058-ALAS) by Dr. Ronald A. Johnson.OWRT AGREEMENT NO. 14-31-0001-5002 PROJECT NO. A-047-ALAS The work upon which this completion report is based was supported by funds provided by the U. S. Department of the Interior, Office of Water Research and Technology, as authorized under the Water Resources Research Act of 1964, Public Law 88-379, as amended

Thermodynamic Entropy And The Accessible States of Some Simple Systems

Comparison of the thermodynamic entropy with Boltzmann's principle shows that under conditions of constant volume the total number of arrangements in simple thermodynamic systems with temperature-independent heat capacities is TC/k. A physical interpretation of this function is given for three such systems; an ideal monatomic gas, an ideal gas of diatomic molecules with rotational motion, and a solid in the Dulong-Petit limit of high temperature. T1/2 emerges as a natural measure of the number of accessible states for a single particle in one dimension. Extension to N particles in three dimensions leads to TC/k as the total number of possible arrangements or microstates. The different microstates of the system are thus shown a posteriori to be equally probable, with probability T-C/k, which implies that for the purposes of counting states the particles of the gas are distinguishable. The most probable energy state of the system is determined by the degeneracy of the microstates.Comment: 9 pages, 1 figur

Teleonomic Entropy: Measuring the Phase-Space of End-Directed Systems

We introduce a novel way of measuring the entropy of a set of values undergoing changes. Such a measure becomes useful when analyzing the temporal development of an algorithm designed to numerically update a collection of values such as artificial neural network weights undergoing adjustments during learning. We measure the entropy as a function of the phase-space of the values, i.e. their magnitude and velocity of change, using a method based on the abstract measure of entropy introduced by the philosopher Rudolf Carnap. By constructing a time-dynamic two-dimensional Voronoi diagram using Voronoi cell generators with coordinates of value- and value-velocity (change of magnitude), the entropy becomes a function of the cell areas. We term this measure teleonomic entropy since it can be used to describe changes in any end-directed (teleonomic) system. The usefulness of the method is llustrated when comparing the different approaches of two search algorithms, a learning artificial neural network and a population of discovering agents

Inquiries into the Nature of Free Energy and Entropy in Respect to Biochemical Thermodynamics

Free energy and entropy are examined in detail from the standpoint of classical thermodynamics. The approach is logically based on the fact that thermodynamic work is mediated by thermal energy through the tendency for nonthermal energy to convert spontaneously into thermal energy and for thermal energy to distribute spontaneously and uniformly within the accessible space. The fact that free energy is a Second-Law, expendable energy that makes it possible for thermodynamic work to be done at finite rates is emphasized. Entropy, as originally defined, is pointed out to be the capacity factor for thermal energy that is hidden with respect to temperature; it serves to evaluate the practical quality of thermal energy and to account for changes in the amounts of latent thermal energies in systems maintained at constant temperature. A major objective was to clarify the means by which free energy is transferred and conserved in sequences of biological reactions coupled by freely diffusible intermediates. In achieving this objective it was found necessary to distinguish between a 'characteristic free energy' possessed by all First-Law energies in amounts equivalent to the amounts of the energies themselves and a 'free energy of concentration' that is intrinsically mechanical and relatively elusive in that it can appear to be free of First-Law energy. The findings in this regard serve to clarify the fact that the transfer of chemical potential energy from one repository to another along sequences of biological reactions of the above sort occurs through transfer of the First-Law energy as thermal energy and transfer of the Second-Law energy as free energy of concentration.Comment: 18-page PDF; major correction in APPENDIX; minor corrections elsewher

New type of phase transition in Reissner Nordstr\"om - AdS black hole and its thermodynamic geometry

The phase transition of a RN-AdS black hole is studied in details using Ehrenfest's equations. There is no discontinuity in entropy which signals a lack of any first order phase transition. We then show that although Ehrenfest's first equation is satisfied, the second is not, so that a true second order phase transition is also ruled out. However this deviation from the second Ehrenfest's equation, for a certain range of the black hole charge, indicates the existence of a new glassy type transition. We finally study the thermodynamic behaviour using state space geometry and find that the scalar curvature diverges exactly at those points where the heat capacity diverges.Comment: Major revisions in Sec. 3. New results and interpretations. 2 new references. To appear in Phys. Lett.

Critical behavior of Born Infeld AdS black holes in higher dimensions

Based on a canonical framework, we investigate the critical behavior of Born-Infeld AdS black holes in higher dimensions. As a special case, considering the appropriate limit, we also analyze the critical phenomena for Reissner Nordstrom AdS black holes. The critical points are marked by the divergences in the heat capacity at constant charge. The static critical exponents associated with various thermodynamic entities are computed and shown to satisfy the thermodynamic scaling laws. These scaling laws have also been found to be compatible with the static scaling hypothesis. Furthermore, we show that the values of these exponents are universal and do not depend on the spatial dimensionality of the AdS space. We also provide a suggestive way to calculate the critical exponents associated with the spatial correlation which satisfy the scaling laws of second kind.Comment: LaTex, 22 pages, 12 figures, minor modifications in text, To appear in Phys. Rev.

Effective thermodynamics of strongly coupled qubits

Interactions between a quantum system and its environment at low temperatures can lead to violations of thermal laws for the system. The source of these violations is the entanglement between system and environment, which prevents the system from entering into a thermal state. On the other hand, for two-state systems, we show that one can define an effective temperature, placing the system into a `pseudo-thermal' state where effective thermal laws are upheld. We then numerically explore these assertions for an n-state system inspired by the spin-boson environment.Comment: 9 pages, 3 figure

Ideal gas sources for the Lemaitre-Tolman-Bondi metrics

New exact solutions emerge by replacing the dust source of the Lem\^aitre-Tolman-Bondi metrics with a viscous fluid satisfying the monatomic gas equation of state. The solutions have a consistent thermodynamical interpretation. The most general transport equation of Extended Irreversible Thermodynamics is satisfied, with phenomenological coefficients bearing a close resemblance to those characterizing a non relativistic Maxwell-Bolzmann gas.Comment: 7 pages, Plain TeX with IOP macros, important corrections to previous version, 3 figures (to appear in Classical and Quantum Gravity, June 1998

Universal restrictions to the conversion of heat into work derived from the analysis of the Nernst theorem as a uniform limit

We revisit the relationship between the Nernst theorem and the Kelvin-Planck statement of the second law. We propose that the exchange of entropy uniformly vanishes as the temperature goes to zero. The analysis of this assumption shows that is equivalent to the fact that the compensation of a Carnot engine scales with the absorbed heat so that the Nernst theorem should be embedded in the statement of the second law. ----- Se analiza la relaci{\'o}n entre el teorema de Nernst y el enunciado de Kelvin-Planck del segundo principio de la termodin{\'a}mica. Se{\~n}alamos el hecho de que el cambio de entrop{\'\i}a tiende uniformemente a cero cuando la temperatura tiende a cero. El an{\'a}lisis de esta hip{\'o}tesis muestra que es equivalente al hecho de que la compensaci{\'o}n de una m{\'a}quina de Carnot escala con el calor absorbido del foco caliente, de forma que el teorema de Nernst puede derivarse del enunciado del segundo principio.Comment: 8pp, 4 ff. Original in english. Also available translation into spanish. Twocolumn format. RevTe