The Carriers of the Interstellar Unidentified Infrared Emission Features: Constraints from the Interstellar C-H Stretching Features at 3.2-3.5 Micrometers

The unidentified infrared emission (UIE) features at 3.3, 6.2, 7.7, 8.6, and 11.3 micrometer, commonly attributed to polycyclic aromatic hydrocarbon (PAH) molecules, have been recently ascribed to mixed aromatic/aliphatic organic nanoparticles. More recently, an upper limit of <9% on the aliphatic fraction (i.e., the fraction of carbon atoms in aliphatic form) of the UIE carriers based on the observed intensities of the 3.4 and 3.3 micrometer emission features by attributing them to aliphatic and aromatic C-H stretching modes, respectively, and assuming A_34./A_3.3~0.68 derived from a small set of aliphatic and aromatic compounds, where A_3.4 and A_3.3 are respectively the band strengths of the 3.4 micrometer aliphatic and 3.3 micrometer aromatic C-H bonds. To improve the estimate of the aliphatic fraction of the UIE carriers, here we analyze 35 UIE sources which exhibit both the 3.3 and 3.4 micrometer C-H features and determine I_3.4/I_3.3, the ratio of the power emitted from the 3.4 micrometer feature to that from the 3.3 micrometer feature. We derive the median ratio to be ~ 0.12. We employ density functional theory and second-order perturbation theory to compute A_3.4/A_3.3 for a range of methyl-substituted PAHs. The resulting A_3.4/A_3.3 ratio well exceeds 1.4, with an average ratio of ~1.76. By attributing the 3.4 micrometer feature exclusively to aliphatic C-H stretch (i.e., neglecting anharmonicity and superhydrogenation), we derive the fraction of C atoms in aliphatic form to be ~2%. We therefore conclude that the UIE emitters are predominantly aromatic.Comment: 14 pages, 5 figures, 1 table; accepted for publication in The Astrophysical Journa

The properties of kaonic nuclei in relativistic mean-field theory

The static properties of some possible light and moderate kaonic nuclei, from C to Ti, are studied in the relativistic mean-field theory. The 1s and 1p state binding energies of $K^-$ are in the range of $73\sim 96$ MeV and $22\sim 63$ MeV, respectively. The binding energies of 1p states increase monotonically with the nucleon number A. The upper limit of the widths are about $42\pm 14$ MeV for the 1s states, and about $71\pm 10$ MeV for the 1p states. The lower limit of the widths are about $12\pm 4$ MeV for the 1s states, and $21\pm 3$ MeV for the 1p states. If $V_{0}\leq 30$ MeV, the discrete $K^-$ bound states should be identified in experiment. The shrinkage effect is found in the possible kaonic nuclei. The interior nuclear density increases obviously, the densest center density is about $2.1\rho_{0}$.Comment: 9 pages, 2 tables and 1 figure, widths are considered, changes a lo

On the momentum-dependence of K−K^{-}-nuclear potentials

The momentum dependent $K^{-}$-nucleus optical potentials are obtained based on the relativistic mean-field theory. By considering the quarks coordinates of $K^-$ meson, we introduced a momentum-dependent "form factor" to modify the coupling vertexes. The parameters in the form factors are determined by fitting the experimental $K^{-}$-nucleus scattering data. It is found that the real part of the optical potentials decrease with increasing $K^-$ momenta, however the imaginary potentials increase at first with increasing momenta up to $P_k=450\sim 550$ MeV and then decrease. By comparing the calculated $K^-$ mean free paths with those from $K^-n$/$K^-p$ scattering data, we suggested that the real potential depth is $V_0\sim 80$ MeV, and the imaginary potential parameter is $W_0\sim 65$ MeV.Comment: 9 pages, 4 figure

A Tale of Two Mysteries in Interstellar Astrophysics: The 2175 Angstrom Extinction Bump and Diffuse Interstellar Bands

The diffuse interstellar bands (DIBs) are ubiquitous absorption spectral features arising from the tenuous material in the space between stars -- the interstellar medium (ISM). Since their first detection nearly nine decades ago, over 400 DIBs have been observed in the visible and near-infrared wavelength range in both the Milky Way and external galaxies, both nearby and distant. However, the identity of the species responsible for these bands remains as one of the most enigmatic mysteries in astrophysics. An equally mysterious interstellar spectral signature is the 2175 Angstrom extinction bump, the strongest absorption feature observed in the ISM. Its carrier also remains unclear since its first detection 46 years ago. Polycyclic aromatic hydrocarbon (PAH) molecules have long been proposed as a candidate for DIBs as their electronic transitions occur in the wavelength range where DIBs are often found. In recent years, the 2175 Angstrom extinction bump is also often attributed to the \pi--\pi* transition in PAHs. If PAHs are indeed responsible for both the 2175 Angstrom extinction feature and DIBs, their strengths may correlate. We perform an extensive literature search for lines of sight for which both the 2175 Angstrom extinction feature and DIBs have been measured. Unfortunately, we found no correlation between the strength of the 2175 Angstrom feature and the equivalent widths of the strongest DIBs. A possible explanation might be that DIBs are produced by small free gas-phase PAH molecules and ions, while the 2175 Angstrom bump is mainly from large PAHs or PAH clusters in condensed phase so that there is no tight correlation between DIBs and the 2175 Angstrom bump.Comment: 45 pages, 3 figures, 4 tables, published in Ap

The Carriers of the "Unidentified" Infrared Emission Features: Clues from Polycyclic Aromatic Hydrocarbons with Aliphatic Sidegroups

The "unidentified" infrared emission (UIE) features at 3.3, 6.2, 7.7, 8.6, and 11.3 $\mu$m are ubiquitously seen in various astrophysical regions. The UIE features are characteristic of the stretching and bending vibrations of aromatic hydrocarbons. The 3.3 $\mu$m feature resulting from aromatic C--H stretches is often accompanied by a weaker feature at 3.4 $\mu$m often attributed to aliphatic C--H stretches. The ratio of the observed intensity of the 3.3 $\mu$m aromatic C--H feature ($I_{3.3}$) to that of the 3.4 $\mu$m aliphatic C--H feature ($I_{3.4}$) allows one to estimate the aliphatic fraction (i.e. $N_{\rm C,aliph}/N_{\rm C,arom}$, the number of C atoms in aliphatic units to that in aromatic rings) of the UIE carriers, provided the intrinsic oscillator strengths of the 3.3 $\mu$m aromatic C--H stretch ($A_{3.3}$) and the 3.4 $\mu$m aliphatic C--H stretch ($A_{3.4}$) are known. In this article we summarize the computational results on $A_{3.3}$ and $A_{3.4}$ and their implications for the aromaticity and aliphaticity of the UIE carriers. We use density functional theory and second-order perturbation theory to derive $A_{3.3}$ and $A_{3.4}$ from the infrared vibrational spectra of seven PAHs with various aliphatic substituents (e.g., methyl-, dimethyl-, ethyl-, propyl-, butyl-PAHs, and PAHs with unsaturated alkyl-chains). The mean band strengths of the aromatic ($A_{3.3}$) and aliphatic ($A_{3.4}$) C--H stretches are derived and then employed to estimate the aliphatic fraction of the UIE carriers by comparing $A_{3.4}$/$A_{3.3}$ with $I_{3.4}$/$I_{3.3}$. We conclude that the UIE emitters are predominantly aromatic, as revealed by the observationally-derived ratio ~ 0.12 and the computationally-derived ratio ~ 1.76 which suggest an upper limit of $N_{\rm C,aliph}/N_{\rm C,arom}$ ~ 0.02 for the aliphatic fraction of the UIE carriers.Comment: 67 pages, 18 figures, 8 tables; invited article accepted for publication in "New Astronomy Review"; a considerable fraction of this article is concerned with the computational techniques and results, readers who are mainly interested in astrophysics may wish to only read "Introduction", and "Astrophysical Implications